Meaning
Chemical breakdown of a polymer resin due to excessive exposure to heat during the processing stage reduces the mechanical and aesthetic properties of the molded part. In typical molding operations, thermal degradation occurs when the melt temperature exceeds the stable range of the polymer or when the resin remains in the heated barrel for too long. This decomposition alters the molecular structure and produces gaseous byproducts that cause cosmetic flaws like splay or surface blistering.
Materials laboratories analyze the molded parts to detect any reduction in average molecular weight.
Thermal Cause
High heater-band settings or excessive mechanical friction generated by the rotating screw can quickly push the plastic past its thermal limits. When thermal degradation occurs, the polymer chains break apart into shorter segments, which dramatically lowers the viscosity of the melt. This thinned material behaves unpredictably in the mold and is highly prone to flashing or uneven shrinkage.
Thermocouples along the barrel must be calibrated regularly to prevent these localized hot spots from forming, as even a minor deviation of five degrees can ruin a sensitive batch of polyoxymethylene resin.
Material Consequence
Degraded parts exhibit a yellowish discoloration, surface streaks, and a substantial loss of impact resistance. This damage is irreversible and prevents the use of the scrapped components as regrind material because the chemical bonds have been permanently altered. If these degraded parts are mixed into the regular production stream, they will cause premature failures in the field.
This risk is especially high in load-bearing applications like automotive brackets or household appliance housings.
Prevention Strategy
Optimizing the shot-to-barrel ratio ensures that the resin does not sit idle for too long, reducing the dwell time.