Meaning
Irreversible chemical structural alteration reduces polymer molecular weight and damages mechanical performance characteristics. Manufacturing engineers study polymer degradation to prevent chain scission, crosslinking and oxidation during processing or outdoor storage. The phenomenon covers thermal, photo-oxidative, mechanical and hydrolytic breakdown mechanisms.
Definition stops at chemical structure breakdown, excluding reversible viscoelastic deformation or elastic strain.
Chemical Breakdown
Molecular weight reduction occurs when excessive barrel temperatures or excessive screw shear break covalent carbon bonds. Processing lines experiencing polymer degradation release volatile organic compounds and show visible discoloration. Chinese environmental protection authorities monitor factory exhaust stack emissions for volatile degradation byproducts during extrusion operations.
Excess thermal shear alters resin viscosity, leading to structural cracking in molded components.
Environmental Stress
Solar radiation and atmospheric oxygen accelerate outdoor polymer breakdown in exposed component applications. Standardized accelerated weathering tests simulate polymer degradation by exposing test bars to ultraviolet radiation and moisture condensation cycles.
Liability Limit
Product liability obligations under Chinese consumer protection statutes hold manufacturers responsible for premature structural failures. Demonstrating that polymer degradation resulted from unapproved regrind additions enables foreign brand owners to enforce contract indemnification clauses against OEM suppliers. Contractual claims require certified laboratory analysis showing chain scission profiles consistent with thermal misprocessing.