Meaning
Chemical metallisation techniques in electronic component manufacturing deposit a layer of palladium onto a substrate without using an external electrical current. This specific plating process, known as electroless palladium, is commonly used as an intermediate barrier layer in printed circuit board surface finishes. The process uses a reducing agent to deposit the metal from an aqueous solution onto a catalytic nickel surface.
Its use is bounded by the high cost of palladium and the necessity of tight control over bath chemistry.
Chemical Deposition
Plating solutions contain palladium salts, complexing agents, and a reducing agent such as sodium hypophosphite. The chemical reduction occurs selectively on active surfaces, allowing the metal to build up uniformly regardless of the shape or size of the features. This autocatalytic reaction continues until the components are removed from the bath.
The resulting deposit contains a small percentage of phosphorus, which influences the mechanical properties of the layer.
Plating Quality
Controlling the deposit thickness is necessary to ensure the integrity of the barrier layer. A thickness between fifty and one hundred nanometres is typical for standard electronics applications. This thin layer is sufficient to prevent the diffusion of nickel into the gold surface, protecting the solder joint from brittle failures.
Assembly Benefit
Using this barrier layer improves the reliability of wire bonding and soldering processes. The palladium prevents the formation of hyper-corrosive nickel states during the subsequent immersion gold step, eliminating the risk of black pad defects. Solder joints formed on these surfaces exhibit higher shear strength and better thermal stability.
This makes the method suitable for high-density interconnects and fine-pitch packages used in mobile devices.