Meaning
Diffusionless phase change in the crystalline structure of steel occurs when the metal is cooled rapidly from its austenitic state. The martensitic transformation is the fundamental mechanism used to harden carbon and alloy steels for industrial tools. Hardening occurs.
This transition happens at a specific temperature range known as the start and finish points for the new phase.
Crystalline Realignment
Atoms move cooperatively over very short distances to form a body-centered tetragonal lattice from the previous face-centered cubic arrangement. During martensitic transformation, the carbon atoms remain trapped within the structure because there is no time for them to migrate. This trapped carbon creates a state of high internal strain that prevents the movement of dislocations through the metal.
Quenching Requirement
Cooling must occur at a rate fast enough to bypass the nose of the transformation curve on a time-temperature-transformation diagram. If the cooling rate is too slow, martensitic transformation is avoided and softer phases like pearlite or bainite form instead. Industrial hardening processes use oil, water, brine or high-pressure gas to achieve the necessary thermal extraction speed for this change.
Mechanical Consequence
Extreme hardness and increased brittle behavior are the primary results of this structural shift in the material. While martensitic transformation provides the strength needed for cutting tools, it also introduces residual stresses that can lead to cracking if not immediately followed by tempering. Strength is gained.
The resulting microstructure is the basis for creating durable wear-resistant surfaces on industrial components. Without this phase change, steel would lack the compressive strength required to withstand the forces of industrial forging or stamping.